
After gas and depreciation, you're looking at break even. If you have a used prius, maybe $1-2/hr. It's a volunteer job and keep in mind that most people who use the service are looking for the cheapest delivery option, so it's unlikely you'll see tips (besides perhaps NY/SF).
Source: I made four deliveries for them (all 1.75x, blitz pricing) to get a feel for their service. It's a great way to fill in time/get some exercise, but unlikely you'll make money. To do that, you'll need a bicycle/scooter (not that I'd want to in NYC/SF) scheduled sessions, and very close proximity to the pickup location.
To be honest, you are probably much better off delivering pizzas (where people are guilt tripped to tip)/starting your own delivery business if the sole object is to make money, unless:
A: you can't work a normal job or are on the brink of poverty, have a bicycle/scooter & live in the pickup zone.
B: you have a cheap, used car that gets 36+ mpg in the city and plan to cherry pick jobs (part time) so you can get all your grocery/x shopping done simultaneously while you are picking up goods for a customer.